US 11,938,686 B2
Multilayer composite composition, its manufacturing process, and article obtained thereof
Michel Glotin, Saint-Cloud (FR); Pierre Gerard, Denguin (FR); Renan Holzmann, Curitiba (FR); and Gilmar Da Costa Lima, Curitiba (FR)
Assigned to Arkema France, Colombes (FR)
Appl. No. 14/760,547
Filed by Arkema France, Colombes (FR); and MVC COMPONENTES PLASTICOS LTDA, Sao Jose Dos Pinhais (BR)
PCT Filed Jan. 15, 2014, PCT No. PCT/EP2014/050711
§ 371(c)(1), (2) Date Jul. 13, 2015,
PCT Pub. No. WO2014/111426, PCT Pub. Date Jul. 24, 2014.
Claims priority of application No. PCT/EP2013/050660 (WO), filed on Jan. 15, 2013.
Prior Publication US 2015/0352818 A1, Dec. 10, 2015
This patent is subject to a terminal disclaimer.
Int. Cl. B29C 70/08 (2006.01); B29B 17/04 (2006.01); B29C 65/00 (2006.01); B29C 70/06 (2006.01); B29C 70/48 (2006.01); B29K 33/00 (2006.01); B29K 55/02 (2006.01); B29K 105/12 (2006.01); B29K 309/08 (2006.01); B29K 633/04 (2006.01); B29K 655/02 (2006.01); B29L 9/00 (2006.01); B32B 27/12 (2006.01); B32B 27/18 (2006.01); B32B 27/30 (2006.01); B32B 27/32 (2006.01); B32B 27/36 (2006.01); B32B 27/40 (2006.01); B32B 37/18 (2006.01); C08J 5/00 (2006.01); B29K 105/06 (2006.01); B32B 38/00 (2006.01); B32B 38/08 (2006.01)
CPC B29C 70/086 (2013.01) [B29C 66/712 (2013.01); B29C 66/7212 (2013.01); B29C 70/06 (2013.01); B29C 70/48 (2013.01); B32B 27/12 (2013.01); B32B 27/18 (2013.01); B32B 27/302 (2013.01); B32B 27/304 (2013.01); B32B 27/32 (2013.01); B32B 27/36 (2013.01); B32B 27/365 (2013.01); B32B 27/40 (2013.01); B32B 37/182 (2013.01); C08J 5/00 (2013.01); B29B 17/04 (2013.01); B29K 2033/08 (2013.01); B29K 2033/12 (2013.01); B29K 2055/02 (2013.01); B29K 2105/06 (2013.01); B29K 2105/12 (2013.01); B29K 2309/08 (2013.01); B29K 2633/12 (2013.01); B29K 2655/02 (2013.01); B29K 2995/0018 (2013.01); B29L 2009/00 (2013.01); B29L 2009/005 (2013.01); B32B 2038/0076 (2013.01); B32B 38/08 (2013.01); B32B 2260/021 (2013.01); B32B 2260/046 (2013.01); B32B 2262/06 (2013.01); B32B 2262/067 (2013.01); B32B 2262/08 (2013.01); B32B 2262/101 (2013.01); B32B 2262/106 (2013.01); B32B 2270/00 (2013.01); B32B 2305/076 (2013.01); B32B 2305/10 (2013.01); B32B 2307/538 (2013.01); B32B 2307/558 (2013.01); B32B 2307/702 (2013.01); B32B 2315/085 (2013.01); B32B 2333/12 (2013.01); B32B 2355/02 (2013.01); B32B 2605/00 (2013.01); C08J 2333/12 (2013.01); C08J 2355/02 (2013.01); C08J 2433/12 (2013.01); C08J 2455/02 (2013.01); Y02W 30/62 (2015.05); Y10T 428/31649 (2015.04)] 21 Claims
OG exemplary drawing
 
1. A multilayer composition for manufacturing mechanical or structured parts or articles comprising
a) a surface layer comprising a thermoplastic polymer A, and
b) a substrate layer comprising a polymeric composite material
wherein said polymeric composite material comprises a polymeric thermoplastic (meth)acrylic matrix selected from the group consisting of a homopolymer or copolymer of methyl(meth)acrylate comprising at least 70% by weight of methyl(meth)acrylate and mixtures thereof, and a fibrous material as reinforcement, wherein the fibrous material comprises discontinuance fibers and wherein said polymeric composite material is formed by the impregnation of said fibrous material with a (meth)acrylic syrup comprising a methyl methacrylate polymer having a weight average molecular weight of greater than 100,000 g/mol, dissolved in a (meth)acrylic monomer wherein said (meth)acrylic monomer comprises methyl methacrylate monomer, followed by polymerization of said (meth)acrylic syrup, wherein said (meth)acrylic syrup has a dynamic viscosity at 25° C. between 10 mPa*s and 10000 mPa*s, and wherein said (meth)acrylic syrup comprises the (meth)acrylic monomer or a mixture of the (meth)acrylic monomers, the methyl methacrylate polymer and at least one initiator or initiating system for starting the polymerization of the (meth)acrylic monomer, wherein said (meth)acrylic syrup forms the polymeric thermoplastic (meth)acrylic matrix,
wherein said impregnation of said fibrous material is made in a closed mold, and wherein said surface layer has a thickness of less than 10 mm.