US 11,866,366 B2
Wear-resistant concrete formulations and methods for their preparation
Dustin A. Hartman, Boggstown, IN (US); William Archie Joseph Shetterley, Fortville, IN (US); and Christopher F. Wolf, Carmel, IN (US)
Assigned to Specification Products, Inc., Noblesville, IN (US)
Filed by Specification Products, Inc., Noblesville, IN (US)
Filed on Sep. 3, 2019, as Appl. No. 16/602,272.
Prior Publication US 2021/0061708 A1, Mar. 4, 2021
Int. Cl. C04B 14/06 (2006.01); E04F 15/12 (2006.01); E01C 19/00 (2006.01); C04B 40/00 (2006.01); C04B 103/00 (2006.01); C04B 111/27 (2006.01); C04B 111/00 (2006.01); C04B 111/60 (2006.01)
CPC C04B 14/062 (2013.01) [C04B 14/06 (2013.01); C04B 40/0032 (2013.01); C04B 40/0039 (2013.01); E01C 19/002 (2013.01); E04F 15/12 (2013.01); C04B 2103/0029 (2013.01); C04B 2111/00008 (2013.01); C04B 2111/27 (2013.01); C04B 2111/60 (2013.01)] 15 Claims
 
1. A process for the preparation of a concrete installation, said process comprising the steps of:
A) creating a concrete mix from components, said components comprising each of the following:
a) a quantity of dry cement mix, said cement mix characterized by:
i) a manufacturer suggested water/cement ratio value; wherein said suggested ratio falls in the range of from about 0.35 to about 0.65; and whereupon combination with b), the water/cement ratio is not greater than the value corresponding to about 30% greater than the suggested value;
or
ii) manufacturer suggested water/cement ratio range, having an upper value and a lower value, and whereupon combination with b) below, the actual water/cement ratio is less than the value corresponding to about 30% greater than the upper value;
or
iii) an amount such that, whereupon combination with b) below, the water/cement ratio is in the range of from about 0.35 to 0.65;
b) a quantity of water,
c) a quantity of amorphous silica of at least about 0.1 ounces per hundredweight of cement in a); wherein the average silica particle size is in the range of from about 1 to about 55 nanometers and/or wherein the surface area of the silica particles is in the range of from about 300 to about 900 m2/g;
d) a quantity of aggregate and/or sand; and
B) wherein the water of b) is added in its entirety or in portions comprising an initial portion, comprising at least about 20 wt % of the quantity of water, and a tailwater portion; wherein the initial portion of water is combined with a) and the components of d) to form a first mix; and wherein the amorphous silica is added to the first mix to form a second mix;
AND
wherein the tailwater is 1) added to the first mix or 2) added to the second mix; or 3) is co-added with the amorphous silica to the first mix, wherein the amorphous silica and the tailwater are, optionally, intercombined; and wherein 1) the first mix is agitated prior to the addition of the tailwater, after the addition of the tailwater, and after the addition of the amorphous silica or 2) the second mix is agitated prior to the addition of the amorphous silica, after the addition of the amorphous silica but before the addition of the tailwater, and after the addition of the tailwater; or 3) the second mix is agitated prior to co-addition of the amorphous silica and the tailwater, and whereupon the concrete mix is then agitated;
OR
C) wherein the quantity of water is added to a) and the components of d) to form a mix, whereupon said mix is agitated for a time ta prior to the addition of the amorphous silica, whereupon the concrete mix is then agitated;
wherein, in the satisfaction of the constraints of B) or C), a silica-comprising mixture results from B) or C), said silica-comprising mixture is mixed for a time greater than about 5 minutes, at a mixing speed of at least 7 RPM;
D) an admixture is added after step B) or step C) to form an admixture-comprising mixture, and said admixture-comprising mixture is mixed, for a total time of at least 3 minutes at one or more speeds greater than about 6 RPM;
E) pouring the concrete mix of D) to form a concrete installation.