US 11,859,049 B2
Preparation method of polyalkylene carbonate
Woosung Hwang, Daejeon (KR); Dongmin Kim, Daejeon (KR); Seung Young Park, Daejeon (KR); Mi Kyung Kim, Daejeon (KR); Joon Ho Shin, Daejeon (KR); and Wonseok Kim, Daejeon (KR)
Assigned to LG Chem, Ltd., Seoul (KR)
Appl. No. 17/273,650
Filed by LG CHEM, LTD., Seoul (KR)
PCT Filed Jul. 7, 2020, PCT No. PCT/KR2020/008828
§ 371(c)(1), (2) Date Mar. 4, 2021,
PCT Pub. No. WO2021/033917, PCT Pub. Date Feb. 25, 2021.
Claims priority of application No. 10-2019-0102577 (KR), filed on Aug. 21, 2019; and application No. 10-2020-0081759 (KR), filed on Jul. 2, 2020.
Prior Publication US 2021/0340318 A1, Nov. 4, 2021
Int. Cl. C08G 64/34 (2006.01); C08G 64/40 (2006.01)
CPC C08G 64/34 (2013.01) [C08G 64/406 (2013.01)] 11 Claims
 
1. A method for preparing a polyalkylene carbonate comprising the steps of:
polymerizing a monomer containing an epoxide compound and carbon dioxide in a solvent in the presence of an organic zinc catalyst to provide a first mixture containing a polyalkylene carbonate, an unreacted epoxide compound, an unreacted carbon dioxide, a residual catalyst, a by-product and a solvent;
removing the unreacted carbon dioxide and the residual catalyst from the first mixture;
removing the unreacted epoxide compound from the first mixture from which the unreacted carbon dioxide and the residual catalyst are removed by using a stripper to provide a second mixture containing the polyalkylene carbonate, the by-product, and the solvent;
heat-exchanging the second mixture;
heating the heat-exchanged second mixture; and
removing the solvent and the by-product from the heated second mixture,
wherein the step of removing the unreacted epoxide compound comprises charging carbon dioxide into the stripper as a stripping agent.